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101.
Mengci He Prof. Hongyan Shi Peng Wang Prof. Xiudong Sun Prof. Bo Gao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16106-16113
Molybdenum carbide (Mo2C) is a promising noble-metal-free electrocatalyst for the hydrogen evolution reaction (HER), due to its structural and electronic merits, such as high conductivity, metallic band states and wide pH applicability. Here, a simple CVD process was developed for synthesis of a Mo2C on carbon cloth (Mo2C@CC) electrode with carbon cloth as carbon source and MoO3 as the Mo precursor. XRD, Raman, XPS and SEM results of Mo2C@CC with different amounts of MoO3 and growth temperatures suggested a two-step synthetic mechanism, and porous Mo2C nanostructures were obtained on carbon cloth with 50 mg MoO3 at 850 °C (Mo2C-850(50)). With the merits of unique porous nanostructures, a low overpotential of 72 mV at current density of 10 mA cm−2 and a small Tafel slope of 52.8 mV dec−1 was achieved for Mo2C-850(50) in 1.0 m KOH. The dual role of carbon cloth as electrode and carbon source resulted into intimate adhesion of Mo2C on carbon cloth, offering fast electron transfer at the interface. Cyclic voltammetry measurements for 5000 cycles revealed that Mo2C@CC had excellent electrochemical stability. This work provides a novel strategy for synthesizing Mo2C and other efficient carbide electrocatalysts for HER and other applications, such as supercapacitors and lithium-ion batteries. 相似文献
102.
Dr. Weixin Zou Lixia Xu Yu Pu Haojie Cai Xiaoqian Wei Yidan Luo Dr. Lulu Li Prof. Dr. Bin Gao Prof. Dr. Haiqin Wan Prof. Dr. Lin Dong 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(19):5058-5064
Bimetallic AgPd nanoparticles have been synthesized before, but the interfacial electronic effects of AgPd on the photocatalytic performance have been investigated less. In this work, the results of hydrogen evolution suggest that the bimetallic AgPd/g-C3N4 sample has superior activity to Ag/g-C3N4 and Pd/g-C3N4 photocatalysts. The UV/Vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, CO adsorption diffuse reflectance FTIR spectroscopy, and FTIR results demonstrate that in the AgPd/g-C3N4, the surface electronic structures of Pd and Ag are changed, which is beneficial for faster photogenerated electron transfer and greater H2O molecule adsorption. In situ ESR spectra suggest that, under visible light irradiation, there is more H2O dissociation to radical species on the AgPd/g-C3N4 photocatalyst. Furthermore, DFT calculations confirm the interfacial electronic effects of AgPd/g-C3N4, that is, Pdδ−⋅⋅⋅Agδ+, and the activation energy of H2O molecule dissociation on AgPd/g-C3N4 is the lowest, which is the main contributor to the enhanced photocatalytic H2 evolution. 相似文献
103.
Mengmeng Ma Ying Wang Nan Gao Xinping Liu Yuhuan Sun Prof. Jinsong Ren Prof. Dr. Xiaogang Qu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(51):11852-11858
Proteolysis of amyloid-β (Aβ) is a promising approach against Alzheimer's disease. However, it is not feasible to employ natural hydrolases directly because of their cumbersome preparation and purification, poor stability, and hazardous immunogenicity. Therefore, artificial enzymes have been developed as potential alternatives to natural hydrolases. Since specific cleavage sites of Aβ are usually embedded inside the β-sheet structures that restrict access by artificial enzymes, this strongly hinders their efficiency for practical applications. Herein, we construct a NIR (near-IR) controllable artificial metalloprotease (MoS2-Co) using a molybdenum disulfide nanosheet (MoS2) and a cobalt complex of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (Codota). Evidenced by detailed experimental and theoretical studies, the NIR-enhanced MoS2-Co can circumvent the restriction by simultaneously inhibition of β-sheet formation and destroying β-sheet structures of the preformed Aβ aggregates in living cell. Furthermore, our designed MoS2-Co is an easy to graft Aβ-target agent that prevents misdirected or undesirable hydrolysis reactions, and has been demonstrated to cross the blood brain barrier. This method can be adapted for hydrolysis of other kinds of amyloids. 相似文献
104.
A linear optical unambiguous discrimination of hyperentangled Bell states is proposed for two‐photon systems entangled in both the polarization and momentum degrees of freedom (DOFs) assisted by time bin. This unambiguous discrimination scheme can completely identify 16 orthogonal hyperentangled Bell states using only linear optical elements, where the function of the auxiliary entangled Bell state is replaced by time bin. Moreover, the possibility of extending this scheme for distinguishing hyperentangled Bell states in n DOFs is discussed, and it shows that hyperentangled Bell states in n ( ) DOFs can be distinguished with k ( ) auxiliary entangled states of additional DOFs by introducing a time delay, which decreases the auxiliary entanglement resource required for unambiguous discrimination of hyperentangled Bell state. Therefore, this scheme provides a new way for distinguishing hyperentangled states with current technology, which will extend the application of discrimination of hyperentangled states via linear optics to other quantum information protocols besides hyperdense coding schemes in the future. 相似文献
105.
Kai Zhao Yulong Xiao Chunxiang Guo Qing Chang Hongfei Gao Xiaohong Cheng 《Tetrahedron》2019,75(3):409-415
Using Suzuki coupling reactions as key steps, a series of fluorenone-based polycatenars, consisting of a central 2,7-diphenyl-9-fluorenone core connected with the 3,4,5-trialkoxybenzoate unit via –COO- linkage at each side have been synthesized. Upon elongation of the terminal alkyl chain, these compounds self-assembled into mesophase sequence of Colhex/p6mm - CubI/ in solid states as well as organogels with interesting morphologies varied from 3D helical fibers to spherical structures in solvents. 相似文献
106.
Xuejie Zhang Yan Xu Andrew K. Abel Leslie S. Smith Roger Watt Amir Hussain Chengxiang Gao 《Entropy (Basel, Switzerland)》2020,22(12)
Extraction of relevant lip features is of continuing interest in the visual speech domain. Using end-to-end feature extraction can produce good results, but at the cost of the results being difficult for humans to comprehend and relate to. We present a new, lightweight feature extraction approach, motivated by human-centric glimpse-based psychological research into facial barcodes, and demonstrate that these simple, easy to extract 3D geometric features (produced using Gabor-based image patches), can successfully be used for speech recognition with LSTM-based machine learning. This approach can successfully extract low dimensionality lip parameters with a minimum of processing. One key difference between using these Gabor-based features and using other features such as traditional DCT, or the current fashion for CNN features is that these are human-centric features that can be visualised and analysed by humans. This means that it is easier to explain and visualise the results. They can also be used for reliable speech recognition, as demonstrated using the Grid corpus. Results for overlapping speakers using our lightweight system gave a recognition rate of over 82%, which compares well to less explainable features in the literature. 相似文献
107.
Chen Li Chen Yu Miao Lili Gao Yiming Di Junwei 《Journal of Solid State Electrochemistry》2020,24(2):411-420
Journal of Solid State Electrochemistry - In this work, we reported the photocurrent switching effect on BiVO4 semiconductor as well as its application for construction of a new cathodic... 相似文献
108.
Acta Mathematicae Applicatae Sinica, English Series - In recent years, there has been a large amount of literature on missing data. Most of them focus on situations where there is only missingness... 相似文献
109.
Xu Jie Wang Kai Li Yi Zhuang Tao-Tao Gao Huai-Ling Liu Yang-Yi He Chuan-Xin Yu Shu-Hong 《中国科学:化学(英文版)》2020,63(8):1046-1052
The increasing demand for the state-of-the-art transparent conductive electrodes has received great interest in synthesizing silver nanowires(AgNWs) with a uniform diameter that exhibit excellent conductance, transparency, flexibility and mechanical ductility. Herein, we report the controllable synthesis of ultrathin AgNWs with high aspect ratio via a polyol-assisted process.The diameter of AgNWs can be continuously modulated from 20 to 80 nm by simply adjusting the aging time. The selfassembled films fabricated by using AgNWs with a diameter of 20 nm as building blocks enable an excellent performance and show a sheet resistance of ~30 Ω/sq and an optical transmittance of 94%. In addition, such nanowire-based conductive films can keep the excellent flexibility and resistance after bending 10,000 cycles. Similarly, the intelligent dimming films prepared by this AgNW films also have excellent flexibility and stability. 相似文献
110.
Liu Yuanyuan Zhou Weibo Liu Haiyan Wei Qianglin Gao Bai Chen Gongxin 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(1):33-42
Journal of Radioanalytical and Nuclear Chemistry - The concentrations of 238U, 226Ra, 232Th and 40K and gross α, β were measured in soils and sediments around a uranium tailings reservoir... 相似文献